Well, I still can't answer that depending on, at least, your goals, and your phenotype.
You seem to be an endo or a meso, or a combination of the two. That said, if I am correct, I'd eat about 50/50 if cutting and 50/100 when bulking, if I were you, then follow it up with the meal you suggested.
I do think immediate consumption is important, because glycogen stores are depleted, protein synthesis is up, and lifting has primed your body for nutrient partitioning.
So for someone your size, I think 25/25 is inadequate. I think your ideas on the next meal are excellent though.
Also, btw, my answer assumes you are getting adequate pre and/or during training nutrition.